Transforming almond shell waste into high-value activators for low-carbon concrete: life cycle assessment and technoeconomic analysis
Low-carbon concrete, including through the use of alkali-activated binders (AABs), is being developed globally to meet construction industry decarbonization goals by reducing reliance on Portland cement (PC). However, the cost and environmental impacts of the alkaline resources conventionally used in AABs are among the factors that have hindered their application. Here, life-cycle assessment (scope A1-A3) and technoeconomic […]
Carbon Sequestration Potential of Cashew (Anacardium occidentale L.) Plantations Across Climatic Gradients in Togo
The current study seeks to estimate the carbon sequestration capability of a cashew plantation in Togo as a function of climate gradient. The research was conducted in the Guinean and Sudanian climatic zones, on farmers’ cashew plantations. The study was run from March to October 2023. This study was carried out in ten (10) cashew […]
Green and sustainable use of macadamia nuts as support material in Pt-based direct methanol fuel cells
The successful commercialization of direct methanol fuel cells (DMFCs) is hindered by inadequate methanol oxidation activity and anode catalyst longevity. Efficient and cost-effective electrode materials are imperative in the widespread use of DMFCs. While Platinum (Pt) remains the primary component of anodic methanol oxidation reaction (MOR) electrocatalysts, its utilization alone in DMFC systems is limited […]
Fe2O3/carbon derived from peanut shell hybrid as an advanced anode for high performance lithium ion batteries
Carbon materials derived from biomass behave sustainability, easy availability, low cost and environmentally benign. And Fe2O3 are considered as promising anodes for high-performance Li-ion batteries (LIBs) because of their rich electrochemical properties, higher theoretical capacity (1007 mAh g−1), non-toxicity, high corrosion resistance and safety. However, the high irreversible capacity loss and poor cycling stability of […]
Walnut By-Products and Elderberry Extracts – Sustainable Alternatives for Human and Plant Health
A current alternative for sustainable development through green chemistry is the replacement of synthetic compounds with natural ones through the superior capitalization of natural resources, with numerous applications in different fields. The benefits of walnuts (Juglans regia L.) and elderberries (Sambucus nigra L.) have been known since ancient times, due to the presence of phytochemicals […]
Characterization of slow pyrolysis products from three different cashew wastes
A huge amount of waste is generated by the cashew processing industries. This study aims to valorise these cashew wastes generated at different levels while processing cashew nuts in factories. The feedstocks include cashew skin, cashew shell and cashew shell de-oiled cake. Slow pyrolysis of these three different cashew wastes was performed at varying temperatures […]
Activated carbon from almond shells using an eco-compatible method: screening, optimization, characterization, and adsorption performance testing.
Activated carbon as a low-cost adsorbent prepared from almond shells using H3PO4 as a chemical activator and room vacuum pyrolysis as a physical activator, which is considered to be an eco-compatible preparation process. Experimental design methodology was used to study and optimize the effects of eight preparation parameters on I2 adsorption expressed by the iodine […]
The Impact of Nutshell Biochar on the Environment as an Alternative Fuel or as a Soil Amendment.
Walnut, pistachio, and peanut nutshells were treated by pyrolysis to biochar and analyzed for their possible usage as fuels or soil fertilizers. All the samples were pyrolyzed to five different temperatures, i.e., 250 °C, 300 °C, 350 °C, 450 °C, and 550 °C. Proximate and elemental analyses were carried out for all the samples, as […]
Development of Low-Cost Porous Carbons through Alkali Activation of Crop Waste for CO2 Capture.
To achieve the “double carbon” (carbon peak and carbon neutrality) target, low-cost CO2 capture at large CO2 emission points is of great importance, during which the development of low-cost CO2 sorbents will play a key role. Here, we chose peanut shells (P) from crop waste as the raw material and KOH and K2CO3 as activators […]
Efficient Remediation of Cadmium- and Lead-Contaminated Water by Using Fe-Modified Date Palm Waste Biochar-Based Adsorbents.
Heavy metals pollution of water resources is an emerging concern worldwide and seeks immediate attention. Date palm waste was transformed into biochar (BC), which was further modified through Fe-intercalation for the production of magnetic biochar (Fe-BC) in this study. The produced BC and Fe-BC were analyzed for chemical, proximate, surface, and elemental composition. The efficiency […]
Laboratory study of water infiltration and evaporation in biochar-amended landfill covers under extreme climate.
Biochar has been used as an environment-friendly enhancer to improve the soil hydraulic properties. Previous studies focused on the effect of biochar addition for irrigation in agricultural soils. However, the understanding of the influence of biochar addition on water infiltration in compacted soils as used in landfill covers is limited. This study investigated the effects […]
Study on performance of carbon source released from fruit shells and the effect on biological denitrification in the advanced treatment.
In order to solve the problem of shortage of carbon source for biological denitrification in advanced treatment of the effluent from secondary treatment of sewage, five kinds of fruit shells (pistachio shell, peanut shell, ginkgo shell, walnut shell and hazelnut shell) were preliminarily selected from eight kinds of fruit shells for experiments of static carbon […]
Activated Carbon from Palm Date Seeds for CO2 Capture.
The process of carbon dioxide capture and storage is seen as a critical strategy to mitigate the so-called greenhouse effect and the planetary climate changes associated with it. In this study, we investigated the CO2 adsorption capacity of various microporous carbon materials originating from palm date seeds (PDS) using green chemistry synthesis. The PDS was […]
Utilization of the UAE date palm leaf biochar in carbon dioxide capture and sequestration processes
This paper evaluates the potential use of date palm leaf biochar as a climate change solution through CO2 capture and sequestration. The pyrolysis of date palm leaf was performed at different temperatures 300°, 400°, 500°, and 600 °C. The physicochemical characteristics of the synthesized biochar were examined using Scanning Electron Microscopy (SEM) with Energy Dispersive X-Ray […]
Green production of hydrochar nut group from waste materials in subcritical water medium and investigation of their adsorption performance for Crystal Violet.
This study evaluates the production of hydrochars from the outer shells of the nut group (peanut, hazelnut, walnut, and pistachio) in an eco-friendly SWM medium and their effects as adsorbents on the removal of crystal violet (CV) from an aqueous solution. The prepared hydrochars were characterized using Brunauer Emmett-Teller (BET) analysis, scanning electron microscope (SEM), […]
An Evaluation of the Impact of the Amount of Potassium Hydroxide on the Porous Structure Development of Activated Carbons.
This paper presents the results of an evaluation of the impact of the amount of potassium hydroxide on the obtained porous structure of the activated carbons derived from the shells of pistachios, hazelnuts, and pecans by carbonization and subsequent chemical activation with potassium hydroxide by different adsorption methods: Brunauer-Emmett-Teller, Dubinin-Raduskevich, the new numerical clustering-based adsorption […]
Adsorption of U (VI) from aqueous solution by using KMnO 4-modified hazelnut shell activated carbon: characterisation and artificial neural network modelling.
This study is based on U(VI) removal from wastewater by KMnO4-modified hazelnut shell activated carbon (KM-HSAC) using adsorption technology. A characterisation study of KM-HSAC was conducted through scanning electron microscope and energy-dispersive X-ray spectroscopy (EDS) analysis. The rough surface of KM-HSAC contains many irregular microspores. The EDS pattern confirmed the U(VI) adsorption on the KM-HSAC. […]
Facile Preparation of Activated Carbon from Peanut Shell for Determination of Bisphenol A in Human Urine by High-Performance Liquid Chromatography.
Herein, a facile and low-cost method for the preparation of activated carbon from peanut shell was developed for the first time for the fast extraction and determination of Bisphenol A in human urine. Bisphenol A was separated by EC-C18 column (250 mm×4.6 mm, 4 μm) and was detected by VWD, with retention time for qualitative […]
Effects of NaOH, thermal, and combined NaOH-thermal pretreatments on the biomethane yields from the anaerobic digestion of walnut shells.
Anaerobic digestion (AD) of walnut shells (WS) results in only a limited biomethane yield because of their high fibre content, which ultimately represents an essentially nonbiodegradable lignocellulosic biomass. In the present study, thermal (i.e. 50-250 °C), alkaline (i.e. 1-5% w/w NaOH) and combined alkaline-thermal (i.e. 4% w/w NaOH + 150 °C thermal) pretreatment methods have […]
Synthesis and Characterization of Activated Carbon from Biowaste-Peanut Shell and Application to Preconcentration/Removal of Uranium.
This study aims to synthesize and characterize an economical and ecological adsorbent with high adsorption capacity. For this purpose, the peanut shells (Pistacia vera L.) were modified chemically. After the synthesis of activated carbon (AC), the optimum conditions for enrichment steps were performed using parameters: pH and contact time for uranium in the model solutions. […]
Carboxyl-functionalized biochar derived from walnut shells with enhanced aqueous adsorption of sulfonamide antibiotics.
The novel HNO3-modifitied biochar (NBC) was synthesized from walnut shell. The NBC was characterized from scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy and Raman spectrum. The NBC was then used in the adsorption of sulfadiazine, sulfamethazine and sulfachloropyridazine from aqueous solution. The material surface has carbon/oxygen-contained groups, which is benefit […]
Elimination of organochlorine pesticides from water by a new activated carbon prepared from Phoenix dactylifera date stones.
This work focused on the characterization of activated carbon (AC) prepared by pyrolysis-chemical activation with phosphoric acid (60%) from date stones derived from three categories of date palm Phoenix dactylifera (Ajwa, Anbari, Khudri), and on its feasibility of elimination of organochlorine pesticides (OCPs) in water samples. The obtained results showed that the three-produced AC date […]
Leaching Performance and Zinc Ions Removal from Industrial Slag Leachate Using Natural and Biochar Walnut Shell.
This study aims to investigate leaching characteristics of zinc slag according to leaching tests, including; TCLP (Toxicity Characteristic Leaching Procedure), SPLP (Synthetic Precipitation Leaching Procedure), ASTM-D3987 (American Society for Testing and Materials), and TS EN-12457-4 (Turkish Standards Institute) tests methods. The present study describes the adsorption potential of natural and biochar walnut shells for removing […]
Analysis and optimisation of a novel ‘almond-refinery’concept: Simultaneous production of biofuels and value-added chemicals by hydrothermal treatment of almond hulls.
For the first time, this work investigates the achievability of developing a biorefinery concept around almond hulls by hydrothermal treatment (HTT), thoroughly scrutinising the influence of the temperature (200-300 °C), pressure (100-180 bar), time (20-180 min) and solid loading (5-25 wt%). This process allowed the conversion of almond hulls into four main products: gas (2-13%), […]
Facile preparation of porous biomass charcoal from peanut shell as adsorbent.
Activated carbons derived from biomass have been proved to be one of the most promising adsorbents due to their abundance, low cost, reproducibility and environmental friendliness. In this study, a simple, facile and effective pyrolysis method was demonstrated to prepare hierarchical porous biomass charcoal by using peanut shells as precursor without chemical activation in an […]
Catalytic ozonation oxidation of ketoprofen by peanut shell-based biochar: Effects of the pyrolysis temperatures.
A series of peanut shell (HS)-based biochar were prepared at different pyrolysis temperatures and subsequently used as the effective ozonation catalysts for ketoprofen (KET) degradation in aqueous solution. The physicochemical properties and morphology of the obtained biochar were analyzed by ICP, TG, XRD, FT-IR, SEM, TEM, BET and etc. characterizations. The results demonstrated that the pyrolysis temperature […]
Influence of biomass components, temperature and pressure on the pyrolysis behavior and biochar properties of pine nut shells.
The aim of this work was to compare the yields, proximate composition, structure and surface morphology of biochar derived from lignin, cellulose, hemicellulose and pine nut shell (PNS) at 400-700 ℃. PNS biochars obtained at different pyrolysis pressures in the range of 0.1-2.0 MPa were also studied. The results indicate that the interactions of lignin, […]